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New nanowire membrane can soak up oil spills
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13:30, June 03, 2008

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A mat of nanowires that feels like paper and can absorb up to 20 times its weight in oil could be an important tool in cleaning up oil spills and other organic pollutants, scientists announced Monday.

MIT researchers and colleagues say they have created a membrane that can be recycled many times for future use and that allows recovery of the oil itself.

"What we found is that we can make 'paper' from an interwoven mesh of nanowires that is able to selectively absorb hydrophobic liquids — oil-like liquids — from water," said Francesco Stellacci, an associate professor in the Department of Materials Science and Engineering and leader of the work.

In addition to its environmental applications, the nanowire paper could also impact filtering and the purification of water, said Jing Kong, an assistant professor of electrical engineering in the Department of Electrical Engineering and Computer Science and one of Stellacci's colleagues on the work. She noted that it could also be inexpensive to produce because the nanowires of which it is composed can be fabricated in larger quantities than other nanomaterials.

The new material appears to be completely impervious to water.

"Our material can be left in water a month or two, and when you take it out it's still dry," Stellacci said. "But at the same time, if that water contains some hydrophobic contaminants, they will get absorbed."

Made of potassium manganese oxide, the nanowires are stable at high temperatures. As a result, oil within a loaded membrane can be removed by heating above the boiling point of oil. The oil evaporates and can be condensed back into a liquid. The membrane — and oil — can be used again.

Two key properties make the system work. First, the nanowires form a spaghetti-like mat with many tiny pores that make for good capillarity, or the ability to absorb liquids. Second, a water-repelling coating keeps water from penetrating into the membrane. Oil, however, isn't affected, and seeps into the membrane.

Source: Xinhua/Agencies



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